These polyphenols, mainly flavonoids with as catechin (flavan-3-ols), epicatechin and procyanidins, give chocolate antioxidant activity. Chocolate also contains additional flavonoids not found in tea, with high concentrations of oligomeric procyanidins.
Chocolates contain both a high quality and a high quantity of phenol antioxidants. Depending on the anthocyanin content, the pigmentation in polyphenol-storage cells ranges from white to deep purple.
Human studies have confirmed that polyphenols in chocolate are indeed bioavailable and able to increase the antioxidant capacity of plasma, with one study reporting that ingestion of 80 g of procyanidin rich-chocolate increased plasma epicatechin concentrations 12-fold.
Polyphenols and alkaloids, ~14 - 20% bean weight, are central to bean flavor character. Three groups of polyphenols can be differentiated: catechins or flvan-3-ols (~37%), anthocyanins (~4%) and proanthocyanidins (~58%).
Dark chocolate has the highest total catechin content, with approximately 53.5 mg/100 g, whereas milk chocolate contains approximately 15.9 mg/100 g. White chocolate primarily contains cocoa butter with minimal levels of polyphenols.
Polyphenols in chocolate and its functions
The word chocolate is derived from the Aztecs names for the tree, and for the drink they prepared from the beans. These words live on in Mexican today as ‘choclatl’ for the drink and ‘cacauatl’ for the tree. Chocolate was first cultivated as a crop, by ancient Mesoamerican peoples. They used cacao beans to create a frothy chocolate drink flavored with spices.
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